Ternary AGa5S8 (A = K, Rb, Cs): Promising infrared nonlinear optical materials rationally realized by “one-for-multiple substitution” strategy

نویسندگان

چکیده

Commercially available infrared (IR) nonlinear optical (NLO) materials, such as diamond-like AgGaQ2 (Q = S, Se), display large NLO coefficients but relatively low laser-induced damage thresholds (LIDTs), which seriously hinder their widespread laser applications. Herein, the “one-for-multiple substitution” strategy, namely, [SZn46+ + 5Zn2+ ⇒ A+ 5Ga3+] (A K, Rb and Cs), is applied on zinc-blende ZnS, affords three new polar ternary crystals AGa5S8 Cs) through solid-state method. These compounds inherit anionic backbone framework in ZnS where functional motifs GaS4 are arranged a parallel manner. This characteristic accounts for remarkable phase-matchable second-harmonic generation intensities (1.1–1.2 × AgGaS2). In addition, inclusion of highly electropositive cations band gap ranging from 3.10 to 3.37 eV, facilitates improvement LIDT (9.3–12.4 To best our knowledge, first series A-inclusion chalcogenides with responses (≥1.0 AgGaS2) wide gaps (≥3.0 eV), fulfilling rigorous requirements outstanding IR materials. strategy presents great significance diamondlike structure evolution provides opportunity achieve

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ژورنال

عنوان ژورنال: Science China. Materials

سال: 2022

ISSN: ['2095-8226', '2199-4501']

DOI: https://doi.org/10.1007/s40843-022-2181-4